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Gas solubility and diffusivity govern how gases permeate, sorb, and migrate through polymers and liquids, influencing barrier properties, storage safety, and catalytic efficiency. In polymers, Henry’s law often provides a baseline solubility for dilute conditions, yet real systems exhibit dual-mode transport, dual-phase partitioning, and plasticization effects at elevated pressures and temperatures. For liquids, solubility is mediated by solvent–gas interactions, with capillary and dissolution dynamics playing a role at microstructural scales. Across both media, diffusivity reflects molecular size, free volume, segmental mobility, and transient free pathways created by thermal motion. Accurate measurements require careful calibration, temperature control, and awareness of sorption hysteresis.

Experimental strategies combine gravimetric, volumetric, and spectroscopic approaches to extract solubility and diffusivity data. Time-lag methods derive diffusivity from transient permeation curves, while constant-volume and constant-pressure setups yield sorption isotherms that reveal partition coefficients. Gas sorption calorimetry links uptake energetics to molecular interactions, and infrared or Raman spectroscopy tracks gas occupancy in specific sites. In polymer matrices, a wide temperature range helps identify glass transition effects and plasticization thresholds, whereas in liquids, viscosity correlations connect molecular mobility to transport rates. Cross-validation among methods improves reliability, and uncertainty quantification helps compare data across laboratories and material generations.

Reproducibility hinges on precise sample preparation, robust sealing, and controlled environmental conditions. For polymers, sample thickness, annealing history, and degree of crystallinity influence gas pathways, while for liquids, miscibility and phase behavior determine uptake limits. An accurate model must accommodate non-idealities such as sorption hysteresis and nonlinear pressure dependence. Experimental designers often choose complementary techniques to capture both solubility and diffusivity under relevant service conditions. Adopting standard reference materials and reporting conventions enhances cross-study comparability, enabling cumulative advances in predictive screening for membranes, coatings, and absorbents.

Modeling approaches span continuum transport equations, segmental dynamics, and molecular simulations that bridge scales from Ångströms to micrometers. Fickian diffusion with pressure-dependent diffusivity can describe simple cases, yet dual-mode transport, Langmuir sorption, and free-volume theories better capture real behavior in polymers. In liquids, free-diffusion models combine with viscoelastic relaxation to reflect time-dependent mobility. Parameter estimation typically employs nonlinear regression, Bayesian inference, or global optimization to fit experimental data, while sensitivity analyses identify influential factors. A robust framework integrates experimental inputs with validated simulations to forecast performance in novel materials and under cyclic loading.

In dense polymer networks, gas molecules encounter a spectrum of microenvironments, from rigid crystalline domains to flexible amorphous chains. Solubility reflects a balance between sorption into free volume and specific interactions with functional groups, such as polar sites or aromatic rings. Diffusivity, meanwhile, depends on segmental motion and the connectivity of free-path networks. Temperature, pressure, and aging alter these properties by expanding or constricting pathways and by inducing plasticization. Researchers must distinguish between reversible and irreversible changes in transport properties to deliver meaningful predictions for long-term deployment in barriers and membranes.

In liquids, solvent polarity, hydrogen bonding, and microstructure modulate gas uptake and diffusion. Mixed solvent systems can create competitive occupancy, where one component displaces another, shifting apparent solubility. Diffusivity often correlates with viscosity and local free-volume fluctuations, yet transient clustering or microheterogeneity may cause departures from simple scaling. Time-resolved methods help separate fast transit from slow rearrangements, clarifying when a system behaves as a simple diffusor or as a dynamic, interacting medium. Cross-technique calibration remains essential to avoid bias from instrument-specific sensitivities or scale-dependent assumptions.

When comparing data sets, it is crucial to document material history, sample geometry, and measurement protocol, including pressure ramp rates and temperature stabilization times. Uncertainty sources include sensor calibration, edge effects, and baseline drift in sorption curves. Clear reporting of units, dimensionless numbers, and model assumptions helps readers judge transferability. Harmonized reporting practices enable meta-analyses that identify systematic biases and guide material design. In addition, open data initiatives and community benchmarks promote reproducibility and accelerate discovery for high-performance barriers, selective membranes, and gas capture systems.

Theoretical developments emphasize coupling between transport and thermodynamics, acknowledging that solubility and diffusivity are not independent. Self-consistent field theories and lattice-based models simulate sorption landscapes, while molecular dynamics sheds light on transient pore connectivity and segmental motion. Multiscale workflows allow researchers to propagate molecular insights into continuum parameters, providing a unified view from microstructure to macroscopic permeability. By embedding uncertainty quantification, these models offer probability-based predictions that inform risk assessments and decision-making in industrial contexts.

Advances in spectroscopic sensing enable site-specific gas tracking within polymers, revealing preferred binding regions and diffusion corridors. Ultra-fast calorimetry captures enthalpic contributions during uptake, linking heats of sorption to affinity and mobility. Microfluidic platforms create controlled environments to observe gas transfer under realistic flow regimes, while micro-tomography visualizes pore networks in situ. In liquids, neutron scattering and X-ray techniques probe density fluctuations and clustering phenomena that influence transport. Together, these tools broaden the parameter space accessible to researchers, improving the fidelity of transport models.

Computational innovations drive predictive capability through more realistic simulations. Enhanced sampling techniques, reactive force fields, and coarse-grained models extend the timescales accessible to study gas transport. Data-driven modeling, including machine learning surrogates, accelerates parameter estimation and enables rapid screening of new material chemistries. When paired with experimental validation, these approaches reduce risk and guide the design of next-generation membranes, sorbents, and separation media. Emphasizing interpretability helps practitioners connect model outputs to material structure and processing routes.

A practical workflow begins with selecting appropriate measurement methods for the material type and target conditions, followed by rigorous calibration and uncertainty analysis. Next, a transport model is built with physically meaningful parameters, whose sensitivity is explored to identify critical design levers. Iterative cycles of experiment and simulation refine both data quality and predictive power. Finally, engineers translate insights into material specifications, validating performance through pilot-scale tests and life-cycle assessments. Recognizing the trade-offs between accuracy, cost, and scalability ensures that research translates into tangible improvements in energy efficiency, safety, and environmental impact.

As the field matures, standardization and collaboration will accelerate progress. Shared benchmarks for gas solubility and diffusivity, open repositories of experimental data, and interoperable software tools empower a diverse community of scientists and engineers. By fostering cross-material comparisons and reproducible workflows, researchers can unlock generalizable principles that apply across polymers and liquids alike. The end goal remains clear: to predict and optimize how gases behave in complex media, enabling smarter materials design, robust industrial processes, and sustainable solutions for a cleaner, safer future.