Stay Plugged In With Canon
Latest News & Updates

Perovskite solar cells promise high efficiency and low manufacturing costs, yet their longevity under real-world operation remains a central challenge. The interfaces inside these devices—between perovskite, electron transport layers, and hole transport layers—are where degradation initiates and propagates. Interfacial engineering seeks to modulate energy alignment, suppress ion migration, and reduce trap-assisted recombination, thereby stabilizing performance over time. By focusing on the microscopic interactions at these boundaries, researchers can slow the onset of performance fade and enable longer service lifetimes. This effort requires careful materials selection, surface treatment, and compatible processing conditions across the device stack.

A core principle in interfacial engineering is control of energy level alignment to facilitate efficient charge extraction while minimizing recombination losses. When energy levels are misaligned, carriers accumulate at interfaces, driving nonradiative pathways that heat and deteriorate adjacent layers. Engineering strategies include incorporating thin interlayers, passivation at defect sites, and molecular tailoring of interface solvents. These approaches aim to create seamless charge transfer channels with low resistance and reduced trap densities. Additionally, protective coatings at the interfaces can shield against moisture and oxygen ingress, which are notorious accelerants of degradation in simulated outdoor environments.

To translate interfacial concepts into real devices, researchers deploy scalable, reproducible fabrication methods that preserve interface integrity. Techniques such as atomic layer deposition, vapor-assisted solution processing, and surface-functionalized ligands enable precise control over thickness, composition, and bonding at interfaces. The challenge is to retain process compatibility with flexible substrates and high-volume manufacturing while maintaining long-term stability. Systematic studies examine how interfacial chemistry responds to thermal cycling, UV exposure, and electrical bias, revealing which treatments persist under stress. The insights guide the selection of materials and processing windows that maximize both efficiency and lifespan.

Wet chemical strategies play a significant role in passivating defects that accumulate at interfaces. By passivating undercoordinated lead ions, halide vacancies, and other trap sites, interfacial treatments reduce nonradiative recombination that dominates efficiency loss during operation. The balance lies in achieving durable passivation without compromising charge transport or triggering unwanted phase changes. Researchers also explore crosslinking networks and salt-additive approaches that strengthen the structural integrity of interfacial regions. These developments contribute to a more resilient device architecture that can withstand daily fluctuations in temperature, humidity, and light exposure.

Environmental robustness hinges on barrier layers that slow moisture ingress into the perovskite layer. Encapsulation is essential, but the choice of interfacial barriers can be equally effective. Ultrathin oxide or organic polymer interlayers can act as moisture sinks, dispersing moisture before it reaches sensitive regions. In parallel, the chemistry at the electron transport layer/perovskite and hole transport layer/perovskite boundaries is optimized to deter ionic movement, a key driver of hysteresis and long-term degradation. The combined effect is a more stable internal environment that supports steady photovoltaic performance under field-like stressors.

Electrical stress poses another dimension of interfacial engineering. Under continuous illumination and bias, charge accumulation at interfaces can trigger localized heating and deterioration of contact materials. Engineers design interfaces to sustain stable work function alignment during operation, minimizing charge build-up. This involves selecting compatible carrier transport materials, tuning interfacial dipoles, and implementing nanoscale smoothing layers that reduce electric field concentrations. By mitigating these effects, devices demonstrate less rapid efficiency decline and preserve open-circuit voltage and fill factor over extended periods.

Ion migration within perovskite structures is a chief contributor to instability, particularly under high humidity and elevated temperatures. Interfacial engineering addresses this by introducing pinning layers and robust chemical environments at critical boundaries. Such layers can impede the movement of iodide or other mobile species, thereby reducing rearrangements that disrupt crystalline quality and energy alignment. The design philosophy emphasizes chemical stability, low diffusion coefficients, and strong adhesion to neighboring layers. Success hinges on harmonizing these properties with the overall device performance to ensure longevity without sacrificing efficiency.

Trap formation at interfaces stems from structural defects and mismatches across materials. Reducing these traps during fabrication translates into fewer nonradiative losses during operation. Advanced passivation strategies employ tailored molecules that bind selectively to defect sites and create a benign interfacial landscape. Some approaches exploit inorganic–organic hybrids to balance rigidity and compatibility. The ultimate goal is to establish a quiet, defect-scarce boundary region that sustains charge transport while maintaining compatibility with scalable manufacturing processes and long-term environmental exposure.

Beyond laboratory demonstrations, practical durability demands compatibility with large-area deposition and panel-level packaging. Scalable interfacial engineering must tolerate thickness variations, solvent residues, and thermal gradients that accompany roll-to-roll or slot-die processes. Researchers test a spectrum of interlayers and surface modifiers to identify formulations that are forgiving of manufacturing tolerances yet still deliver enduring performance. Importantly, these efforts balance cost, environmental impact, and recyclability, aiming to produce devices that are not only efficient but also resilient and commercially viable under sustained operation.

Long-term testing under accelerated aging conditions provides critical feedback for interfacial strategies. Protocols simulate daily operating cycles, elevated temperatures, and humidity stress, while monitoring changes in key metrics such as efficiency, fill factor, and spectral response. Data from these tests guide iterative improvements in interfacial coatings and material choices. The resulting designs typically exhibit reduced degradation rates, delayed onset of failure modes, and smoother performance decline profiles, which are essential for consumer confidence and grid-scale deployment.

As interfacial engineering matures, multidisciplinary collaboration becomes increasingly important. Chemists, physicists, and engineers combine insights from spectroscopy, microscopy, and device physics to map degradation pathways at nanoscale interfaces. This holistic view enables targeted interventions that address specific mechanisms—ion migration, defect creation, humidity ingress, and electrode corrosion. The most promising approaches integrate adaptive interfaces that respond to local conditions, providing dynamic protection without hindering charge extraction. Ultimately, robust interfacial design supports not just higher efficiency, but also reliable performance across diverse climates and operating lifetimes.

Looking ahead, advances in interfacial engineering may unlock new perovskite compositions and tandem architectures with intrinsic stability advantages. Smart interfaces could sense stress signals and autonomously adjust barrier properties, while compatible manufacturing ecosystems ensure reproducible results at scale. The convergence of materials science, computational modeling, and lifecycle assessment will guide the deployment of durable cells from pilot facilities to commercial installations. In this evolving landscape, the role of carefully engineered boundaries remains central to achieving long-lasting, high-performance perovskite solar energy.